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FIELD STUDIES: Sacramento-San Joaquin Delta

SEASONAL PESTICIDE CONCENTRATIONS IN THE DELTA

Map of Field Study Area

The Sacramento–San Joaquin Delta (Delta) of California is an ecologically rich and hydrologically complex region that receives runoff from nearly one-quarter of the state. Water quality studies of surface water in the region have found dissolved pesticides in winter storm runoff at concentrations toxic to some aquatic invertebrates. However, scientists have little information on pesticide concentrations in the Delta on a seasonal timescale or the importance of pesticide contributions from within-Delta sources. Consequently, a study was conducted from 1994 to 1996 during which water samples were collected seasonally from 31 sites located within the Delta and on major tributaries to the Delta. Water samples were analyzed for 20 current-use pesticides and dissolved organic carbon. During the study, 11 current-use pesticides were detected; maximum concentrations ranging from 17 ng/L (for trifluralin) to 1,160 ng/L (for metolachlor). The highest concentrations of five pesticides (carbaryl, carbofuran, metolachlor, molinate, and simazine) were greater than 900 ng/L. The greatest number of pesticides was detected in the summer of 1994, whereas the least number were detected in the winter of 1994. The herbicides metolachlor and simazine were the most frequently detected pesticides and were detected in five of the six sampling seasons. The herbicides molinate and EPTC were detected only during the three summer sampling seasons. A comparison of pesticides detected during the spring and summer of 1995 showed some seasonal variability. Comparison of the three summer seasons sampled showed that a larger number of pesticides were detected, and with generally higher maximum concentrations, in 1994 than in 1995 or 1996.

Orlando, J.L. and Kuivila, K.M., 2006, Seasonal Changes in Concentrations of Dissolved Pesticides and Organic Carbon in the Sacramento–San Joaquin Delta, California, 1994– 1996: U.S. Geological Survey Data Series 197, 32 p.

SACRAMENTO VALLEY RICE PESTICIDES

Map of Field Study Area

Crop Duster airplane

Pesticides applied to rice fields in California are transported into the Sacramento River watershed by the release of rice field water. Despite monitoring and mitigation programs, concentrations of two rice pesticides, molinate and thiobencarb, continue to exceed surface-water concentration performance goals established by the Central Valley Regional Water Quality Control Board. There have been major changes in rice pesticide use over the past decade, molinate use has declined by nearly half, while thiobencarb use has more than doubled; carbofuran has been eliminated and partially replaced by the pyrethroid pesticide lambda-cyhalothrin.

A study was conducted in 2002 and 2003 by the U.S. Geological Survey to determine if the changes in pesticide use on rice resulted in corresponding changes in pesticide concentrations in surface waters. During the rice growing season (May–July), water samples, collected weekly at three sites in 2002 and two sites in 2003, were analyzed for pesticides using both solid-phase and liquid-liquid extraction in combination with gas chromatography/mass spectrometry. Analytes included lambda-cyhalothrin, molinate, thiobencarb, and two degradation products of molinate: 2-keto-molinate and 4-keto-molinate.

Molinate, thiobencarb, and 4-keto-molinate were detected in all samples, 2-keto-molinate was detected in less than half of the samples, and lambda-cyhalothrin was not detected in any samples. At two of the sites sampled in 2002 (Colusa Basin Drain 1 and Sacramento Slough), concentrations of molinate were similar, but thiobencarb concentrations differed by a factor of five. Although concentrations cannot be estimated directly from application amounts in different watersheds, the ratio of molinate to thiobencarb concentrations can be compared with the ratio of molinate to thiobencarb use in the basins. The higher concentration ratio in the Sacramento Slough Basin, compared with the ratio in the basin area feeding the Colusa Basin Drain 1, is consistent with the higher use ratio, suggesting that differences in application amounts can explain the observed concentration differences. The samples from the downstream site (Tower) sampled in 2002 had the lowest concentrations of pesticides. Performance goals were exceeded for either molinate or thiobencarb in six samples from the upstream sites, but not in any samples from the downstream Tower site. In 2003, concentrations at upstream sites were much lower than the previous year with only one sample containing thiobencarb at a concentration above the performance goal. Lower concentrations could be partially due to delays in rice planting and pesticide application owing to spring rainstorms.

Orlando, J.L., and Kuivila, K.M., 2004, Changes in rice pesticide use and surface water concentrations in the Sacramento River watershed, California: U.S. Geological Survey Scientific Investigations Report 2004–5097, 28 p.

Kuivila, K.M. and Jennings, B.E., 2007, Input, flux, and persistence of six select pesticides in San Francisco Bay, Int. J. Environ. Anal. Chem. 87:13, 897 – 911.

Crepeau, K.L., and Kuivila, K.M., 2000, Factors controlling rice pesticide concentrations in the Colusa Basin Drain and the Sacramento River, California, 1990-1993, J. Environmental Quality, vol 29(3), pp 926-935.

PESTICIDE CONCENTRATIONS DURING MANAGED FLOW CONDITIONS

Map of Field Study Area

Concentrations of organic contaminants were determined in water samples collected at six surface-water sites located along the San Joaquin and Old Rivers during April through June 2001. Water samples were collected, coincident with salmon smolt caging studies conducted by researchers from the Bodega Marine Laboratory at the University of California at Davis to characterize exposure of the salmon smolt to organic contaminants. Sampling occurred prior to, during, and following the implementation of managed streamflow conditions on the San Joaquin and Old Rivers as part of the Vernalis Adaptive Management Plan. Thirteen pesticides were detected in water samples collected during this study, and at least five pesticides were detected in each sample. The total number of pesticide detections varied little between river systems and between sites, but the maximum concentrations of most pesticides occurred in San Joaquin River samples. The total number of pesticides detected varied little over the three time periods. However, during the period of managed streamflow, the fewest number of pesticides were detected at their absolute maximum concentration. Nine wastewater compounds were detected during this study. Suspended-sediment concentrations were similar for the San Joaquin and Old Rivers except during the period of managed streamflow conditions, when suspended-sediment concentration was higher at sites on the San Joaquin River than at sites on the Old River. Values for water parameters (pH, specific conductance, and hardness) were lowest during the period of managed flows.

Orlando, J.L., and Kuivila, K.M., 2005, Concentrations of organic contaminants detected during managed flow conditions, San Joaquin River and Old River, California, 2001: U.S. Geological Survey Data Series 120, 13 p.

PESTICIDE CONCENTRATIONS IN SALMON HABITAT

Salmon Habitat Map

Field and laboratory studies were conducted to determine the effects of pesticide mixtures on Chinook salmon under various environmental conditions in surface waters of the northern Central Valley of California. The project focused on understanding the environmental factors that influence the toxicity of pesticides to juvenile salmon and their prey. During the periods January through April 2001 and January through May 2002, water samples were collected at eight surface water sites in the northern Central Valley of California and analyzed for dissolved pesticide and organic carbon concentrations, and aquatic toxicity associated with winter storm runoff concurrent with winter run Chinook salmon out-migration. Sites were selected that represented the primary habitat of juvenile Chinook salmon and included major tributaries within the Sacramento and San Joaquin River Basins and the Sacramento–San Joaquin Delta. Water samples were collected daily for a period of seven days during two winter storm events in each year. Additional samples were collected weekly during January through April or May in both years. Concentrations of 31 currently used pesticides were measured in filtered water samples using solid-phase extraction and gas chromatography-mass spectrometry.

Orlando, J.L., Jacobson, L.A., and Kuivila, K.M., 2004, Dissolved pesticide and organic carbon concentrations detected in surface waters, northern Central Valley, California, 2001–2002: U.S. Geological Survey Open-File Report 2004–1214, 32 p.

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